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Alloy

Definition and Classification of Alloys

  • An alloy is a mixture of chemical elements, with at least one being a metal.
  • Alloys retain the properties of metals, such as electrical conductivity and luster.
  • Alloys may have different properties than the pure metals, such as increased strength or hardness.
  • Some alloys can reduce the overall cost of a material while preserving important properties.
  • Metallic bonding joins the atoms in an alloy, unlike covalent bonds found in chemical compounds.
  • Alloys are classified as substitutional or interstitial, based on the atomic arrangement.
  • They can be homogeneous (single phase) or heterogeneous (multiple phases).
  • Alloys can be solid solutions of metal elements or mixtures of metallic phases.
  • The constituents of alloys are measured by mass percentage or atomic fraction.
  • Intermetallic alloys have a specific atomic arrangement and properties.

Examples and Applications of Alloys

  • Red gold (gold and copper) and white gold (gold and silver) are examples of alloys.
  • Sterling silver is an alloy of silver and copper.
  • Steel and silicon steel are alloys of iron with carbon or silicon, respectively.
  • Solder, brass, pewter, duralumin, bronze, and amalgams are also alloys.
  • Alloys like beryllium-copper are used for non-sparking tools.
  • Steel alloys are used in buildings, automobiles, and surgical tools.
  • Titanium alloys are used in the aerospace industry.
  • Beryllium-copper alloys are used for non-sparking tools.
  • Alloys like duralumin find applications in the aviation industry.
  • Exotic alloys like Inconel are used in high-temperature environments.

Alloy Formation, Impurities, and Properties

  • Alloys are formed by mixing two or more elements, with one being a metal.
  • The mechanical properties of alloys can be different from their individual constituents.
  • Some alloys form solid solutions, while others have a heterogeneous microstructure.
  • Impurities in alloys can have detrimental effects on their properties.
  • Care is taken during alloying to remove excess impurities using various methods.
  • Alloys are strong solvents that can dissolve most metals and elements.
  • They readily absorb gases like oxygen and can burn in the presence of nitrogen.
  • Alloys must be melted in vacuum induction-heating and special, water-cooled, copper crucibles to avoid contamination.
  • Alloying can be done with one or more constituents in a gaseous state or in the solid state.
  • By adding another element to a metal, internal stresses are created in the lattice of metallic crystals, enhancing its properties.

Alloying Elements and Heat Treatment

  • Alloying elements are added to a base metal to induce desired properties.
  • Most metals and alloys can be work hardened by creating defects in their crystal structure.
  • Alloys can have their properties altered by heat treatment.
  • Many alloys of aluminum, copper, magnesium, titanium, and nickel can be strengthened by heat treatment.
  • Steel undergoes a change in the arrangement of its atoms when alloyed with carbon.
  • Allotropes of iron, such as alpha iron and gamma iron, show differences in atomic arrangement.
  • Alloying elements can be dissolved in iron, forming a homogeneous phase called austenite.
  • Slow cooling of steel allows carbon atoms to precipitate out, forming cementite and ferrite phases.
  • Rapid cooling of steel traps carbon atoms within iron crystals, forming a hard but brittle phase called martensite.
  • Precipitation hardening alloys soften when quenched and then harden over time.

History and Examples of Alloys

  • Alloys have been used by humans since ancient times.
  • The use of alloys started with meteoric iron, a naturally occurring alloy of nickel and iron.
  • Bronze and brass are examples of substitutional alloys.
  • Steel is an example of an interstitial alloy.
  • Stainless steel is a combination of interstitial and substitutional alloys.
  • Meteoric iron was used to make tools, weapons, and nails.
  • Bronze is an alloy of copper and tin, while brass is an alloy of copper and zinc.
  • Amalgams are alloys in a soft paste or liquid form at ambient temperature.
  • Gold was often alloyed with copper or iron for aesthetic purposes.
  • Pewter is an alloy primarily consisting of tin.

Alloy Data Sources

Reference URL
Glossary https://harryandcojewellery.com.au/blogs/glossary/alloy
Wikipedia http://en.wikipedia.org/wiki/Alloy
Wikidata https://www.wikidata.org/wiki/Q37756
Knowledge Graph https://www.google.com/search?kgmid=/m/0hq_nhc